- Benefits of Organic Photochemistry -
When a molecule is irradiated with a frequency that matches the energy difference between ground and excited state, a photochemical reaction may occur. These type of reactions differ significantly form the traditional reactions:
- The excited states are rich in energy. Therefore reactions may occur that are highly
endothermic in the ground state.
- In the excited state antibonding orbitals are occupied. This may allow reactions which are
not possible for electronic reasons in the ground state.
- Photochemical reaction can include singlet and triplet states. Thermal reactions usually
only show singlet states. In photochemical reaction intermediates may be formed which
are not accessible at thermal conditions.
- Directory Contents -
The web site "Organic Photochemistry" is an excellent starting point for both a researcher new to the field as an expert who is looking for a intuitively organized web site about this subject.
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